Chapter-4 Carbon and its component
Question 1:
What would be the electron dot structure of carbon dioxide
which has the formula CO2?
Answer:
Electron dot structure of CO2 is

Question 2:
What would be the electron dot
structure of a molecule of sulphur which is made up of eight atoms of sulphur?
(Hint − the eight atoms of sulphur are joined together in the form of a ring.)
Answer:
Electron dot structure of a sulphur molecule

Question 1:
How many structural isomers can you draw for pentane?
Answer:
Three structural isomers are possible for pentane.

Question 2:
What are the two properties of
carbon which lead to the huge number of carbon compounds we see around us?
Answer:
The two features of carbon that
give rise to a large number of compounds are as follows: (i) Catenation − It is
the ability to form bonds with other atoms of carbon.
(ii) Tetravalency − With the
valency of four, carbon is capable of bonding with four other atoms.
Question 3:
What will be the formula and electron dot structure of
cyclopentane?
Answer:
The formula for cyclopentane is C5H10.
Its electron dot structure is given below.

Question 4:
Draw the structures for the following compounds.
(i) Ethanoic acid (ii) Bromopentane*
(iii) Butanone (iv) Hexanal
*Are structural isomers possible for bromopentane?
Answer:
(i)

(ii) There are many structural isomers possible for
bromopentane. Among them, the

Why do ionic compounds have high melting points?
Answer:
Ionic compounds have strong
electrostatic forces of attraction between the ions. Therefore, it requires a
lot of energy to overcome these forces. That is why ionic compounds have high
melting points.
Question 1:
Why is the conversion of ethanol to ethanoic acid an
oxidation reaction?
Answer:

Since the conversion of ethanol to
ethanoic acid involves the addition of oxygen to ethanol, it is an oxidation
reaction.
Question 2:
A mixture of oxygen and ethyne is
burnt for welding. Can you tell why a mixture of ethyne and air is not used?
Answer:

When ethyne is burnt in air, it
gives a sooty flame. This is due to incomplete combustion caused by limited
supply of air. However, if ethyne is burnt with oxygen, it gives a clean flame
with temperature 3000°C because of complete combustion. This oxy-acetylene
flame is used for welding. It is not possible to attain such a high temperature
without mixing oxygen. This is the reason why a mixture of ethyne and air is
not used.
Question 1:
How would you distinguish experimentally between an alcohol
and a carboxylic acid?
Answer:
We can
distinguish between an alcohol and a carboxylic acid on the basis of their
reaction with carbonates and hydrogen carbonates. Acid reacts with carbonate
and hydrogen carbonate to evolve CO2 gas that turns lime water
milky.

Alcohols, on the other hand, do not react with carbonates
and hydrogen carbonates.
Question 2:
What are oxidising agents?
Answer:
Some substances such as alkaline potassium permanganate and
acidified potassium dichromate are capable of adding oxygen to others. These
are known as oxidising agents.
Question 1:
Would you be able to check if water is hard by using a
detergent?
Answer:
Detergents are ammonium or
sulphonate salts of long chain carboxylic acids. Unlike soap, they do not react
with calcium and magnesium ions present in hard water to form scum. They give a
good amount of lather irrespective of whether the water is hard or soft. This
means that detergents can be used in both soft and hard water. Therefore, it
cannot be used to check whether the water is hard or not.
Question 2:
People use a variety of methods to
wash clothes. Usually after adding the soap, they ‘beat’ the clothes on a
stone, or beat it with a paddle, scrub with a brush or the mixture is agitated
in a washing machine. Why is agitation necessary to get clean clothes?
Answer:
A soap molecule has two parts
namely hydrophobic and hydrophilic. With the help of these, it attaches to the
grease or dirt particle and forms a cluster called micelle. These micelles
remain suspended as a colloid. To remove these micelles (entrapping the dirt),
it is necessary to agitate clothes.
Question 1:
Ethane,
with the molecular formula C2H6 has (a) 6 covalent bonds.
(b) 7 covalent bonds.
(c) 8 covalent
bonds.
(d) 9 covalent
bonds.
Answer:
(b) Ethane has 7
covalent bonds.
Question 2:
Butanone is a
four-carbon compound with the functional group (a) carboxylic acid.
(b) aldehyde.
(c) ketone.
(d) alcohol.
Answer:
(c) The functional group of butanone is
ketone.
Question 3:
While cooking, if the bottom of the
vessel is getting blackened on the outside, it means that
(a) the food
is not cooked completely. (b) the fuel is not burning completely.
(c) the fuel is
wet.
(d) the fuel is
burning completely.
Answer:
(b) While cooking, if the bottom of the vessel
is getting blackened on the outside, then it means that the fuel is not burning
completely.
Question 4:
Explain the nature of the covalent bond using the bond
formation in CH3Cl.
Answer:
Carbon can
neither lose four of its electrons nor gain four electrons as both the
processes require extra amount of energy and would make the system unstable.
Therefore, it completes its octet by sharing its four electrons with other
carbon atoms or with atoms of other elements. The bonds that are formed by
sharing electrons are known as covalent bonds. In covalent bonding, both the
atoms share the valence electrons, i.e., the shared electrons belong to the
valence shells of both the atoms.

Here, carbon requires 4 electrons
to complete its octet, while each hydrogen atom requires one electron to
complete its duplet. Also, chlorine requires an electron to complete the octet.
Therefore, all of these share the electrons and as a result, carbon forms 3
bonds with hydrogen and one with chlorine.
Question 5:
Draw the
electron dot structures for (a) ethanoic acid.
(b) H2S.
(c) propanone.
(d) F2.
Answer:

What is a homologous series? Explain with an example.
Answer:
A homologous series is a series of
carbon compounds that have different numbers of carbon atoms but contain the
same functional group.
For example, methane, ethane,
propane, butane, etc. are all part of the alkane homologous series. The general
formula of this series is CnH2n+2.
Methane CH4
Ethane CH3CH3
Propane CH3CH2CH3
Butane CH3CH2CH2CH3
It can be noticed that there is a
difference of −CH2 unit between each successive compound.
Question 7:
How can ethanol and ethanoic acid
be differentiated on the basis of their physical and chemical properties?
Answer:
•
Ethanol is a liquid at room temperature with a pleasant
odour while ethanoic acid has vinegar-like smell. The melting point of ethanoic
acid is 17°C. This is below room temperature and hence, it freezes during
winters.
•
Ethanoic acid reacts with metal carbonates and metal
hydrogencarbonates to form salt, water, and carbon dioxide gas while ethanol
does not react with them.


In the electrolytic refining of a
metal M, what would you take as the anode, the cathode and the electrolyte?
Answer:
In the electrolytic refining of a metal M:
Anode → Impure metal M
Cathode
→
Thin strip of pure metal M Electrolyte → Solution of salt of the metal M Question 9:
Why are carbon and its compounds used as fuels for most
applications?
Answer:
Most of the carbon compounds give a
lot of heat and light when burnt in air. Saturated hydrocarbons burn with a
clean flame and no smoke is produced. The carbon compounds, used as a fuel,
have high calorific values. Therefore, carbon and its compounds are used as
fuels for most applications.
Question 10:
Explain the formation of scum when hard water is treated
with soap.
Answer:
Soap does not work properly when
the water is hard. A soap is a sodium or potassium salt of long chain fatty
acids. Hard water contains salts of calcium and magnesium. When soap is added
to hard water, calcium and magnesium ions present in water displace sodium or
potassium ions from the soap molecules forming an insoluble substance called
scum. A lot of soap is wasted in the process.
Question 11:
What change will you observe if you test soap with litmus
paper (red and blue)?
Answer:
Since soap is basic in nature, it
will turn red litmus blue. However, the colour of blue litmus will remain blue.
Question 12:
What is hydrogenation? What is its industrial application?
Answer:
Hydrogenation
is the process of addition of hydrogen. Unsaturated hydrocarbons are added with
hydrogen in the presence of palladium and nickel catalysts to give saturated
hydrocarbons.

This reaction is applied in the
hydrogenation of vegetables oils, which contain long chains of unsaturated
carbons.
Question 13:
Which of the following hydrocarbons undergo addition
reactions:
C2H6, C3H8, C3H6,
C2H2 and CH4.
Answer:
Unsaturated hydrocarbons undergo addition reactions. Being
unsaturated hydrocarbons,
C3H6 and C2H2
undergo addition reactions.
Question 14:
Give a test that can be used to differentiate chemically
between butter and cooking oil.
Answer:
Butter contains saturated fats.
Therefore, it cannot be hydrogenated. On the other hand, oil has unsaturated
fats. That is why it can be hydrogenated to saturated fats (solids).
Question 15:
Explain the mechanism of the cleaning action of soaps.
Answer:
Cleansing action of soaps:
The dirt
present on clothes is organic in nature and insoluble in water. Therefore, it
cannot be removed by only washing with water. When soap is dissolved in water,
its hydrophobic ends attach themselves to the dirt and remove it from the
cloth. Then, the molecules of soap arrange themselves in micelle formation and
trap the dirt at the centre of the cluster. These micelles remain suspended in
the water. Hence, the dust particles are easily rinsed away by water.

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