Chapter 2 Questions Answer
Question 1:
You have been provided with three
test tubes. One of them contains distilled water and the other two contain an
acidic solution and a basic solution, respectively. If you are given only red
litmus paper, how will you identify the contents of each test tube?
Answer
If the colour of red litmus paper
gets changed to blue, then it is a base and if there is no colour change, then
it is either acidic or neutral. Thus, basic solution can be easily
identified.
Let us mark the three test tubes as
A, B, and C. A drop of the
solution in A is put on the red
litmus paper. Same is repeated with solution B and C. If either of
them changes colour to blue, then it is basic. Therefore, out of three, one is
eliminated. Out of the remaining two, any one can be acidic or neutral. Now a
drop of basic solution is mixed with a drop of each of the remaining two
solutions separately and then the nature of the drops of the mixtures is
checked. If the colour of red litmus turns blue, then the second solution is
neutral and if there is no change in colour, then the second solution is
acidic. This is because acidic and basic solutions neutralize each other.
Hence, we can distinguish between the three types of solutions.
Why should curd and sour substances not be kept in brass and
copper vessels?
Answer
Curd and other sour substances contain acids. Therefore,
when they are
kept in brass and copper vessels,
the metal reacts with the acid to liberate hydrogen gas and harmful products,
thereby spoiling the food.
Question 2:
Which gas is usually liberated when
an acid reacts with a metal? Illustrate with an example. How will you test for
the presence of this gas?
Answer
Hydrogen gas is usually liberated when an acid reacts with a
metal.

Take few pieces of zinc granules
and add 5 ml of dilute H2SO4. Shake it and pass the gas
produced into a soap solution. The bubbles of the soap solution are formed.
These soap bubbles contain hydrogen gas.

We can test the evolved hydrogen
gas by its burning with a pop sound when a candle is brought near the soap
bubbles.
Question 3:
Metal compound A reacts with dilute
hydrochloric acid to produce effervescence. The gas evolved extinguishes a
burning candle. Write a balanced chemical equation for the reaction if one of
the compounds formed is calcium chloride.
Answer

Why do HCl, HNO3, etc.,
show acidic characters in aqueous solutions while solutions of compounds like
alcohol and glucose do not show acidic character?
Answer
The dissociation of HCl or HNO3
to form hydrogen ions always occurs in the presence of water. Hydrogen ions (H+)
combine with H2O to form hydronium ions (H3O+).
The reaction is as follows:

Although aqueous solutions of
glucose and alcohol contain hydrogen, these cannot dissociate in water to form
hydrogen ions. Hence, they do not show acidic character.
Question 2:
Why does an aqueous solution of an acid conduct electricity?
Answer
Acids dissociate in aqueous
solutions to form ions. These ions are responsible for conduction of
electricity.
Question 3:
Why does dry HCl gas not change the colour of the dry litmus
paper?
Answer
Colour of the litmus paper is
changed by the hydrogen ions. Dry HCl gas does not contain H+ ions.
It is only in the aqueous solution that an acid dissociates to give ions. Since
in this case, neither HCl is in the aqueous form nor the litmus paper is wet, therefore,
the colour of the litmus paper does not change.
Question 4:
While diluting an acid, why is it
recommended that the acid should be added to water and not water to the acid?
Answer
Since the process of dissolving an
acid in water is exothermic, it is always recommended that acid should be added
to water. If it is done the other way, then it is possible that because of the
large amount of heat generated, the mixture splashes out and causes burns.
Question 5:
How is the concentration of hydronium
ions (H3O+) affected when a solution of an acid is
diluted?
Answer
When an acid is diluted, the
concentration of hydronium ions (H3O+) per unit volume
decreases. This means that the strength of the acid decreases.
Question 6:
How is the concentration of
hydroxide ions (OH−) affected when excess base is dissolved in a
solution of sodium hydroxide?
Answer
The concentration of hydroxide ions
(OH−) would increase when excess base is dissolved in a solution of
sodium hydroxide.
You have two solutions, A and B.
The pH of solution A is 6 and pH of solution B is 8. Which solution has more
hydrogen ion concentration? Which of this is acidic and which one is basic?
Answer
A pH value of less than 7 indicates
an acidic solution, while greater than 7 indicates a basic solution. Therefore,
the solution with pH = 6 is acidic and has more hydrogen ion concentration than
the solution of pH = 8 which is basic.
Question 2:
What effect does the concentration of
ions have on the nature of the
solution?

Answer
Concentration of
can have a varied effect on the
nature of the solution. With an increase in H+ ion concentration,
the solution becomes more acidic, while a decrease of H+ ion causes
an increase in the basicity of the solution.

Question 3:

Answer
Yes, basic solution also has ions.
However, their concentration is less as compared to the concentration of OH−
ions that makes the solution basic.
Question 4:
Under what soil condition do you
think a farmer would treat the soil of his fields with quick lime (calcium
oxide) or slaked lime (calcium hydroxide) or chalk (calcium carbonate)?
Answer
If the soil is acidic and improper
for cultivation, then to increase the basicity of soil, the farmer would treat
the soil with quick lime or slaked lime or chalk.
Question 1:
What is the common name of the compound CaOCl2?
Answer
The common name of the compound CaOCl2 is
bleaching powder.
Question 2:
Name the substance which on treatment with chlorine yields
bleaching powder?
Answer
Calcium hydroxide [Ca (OH)2], on treatment with
chlorine, yields bleaching powder.
Question 3:
Name the sodium compound which is used for softening hard water.
Answer
Washing soda (Na2CO3.10H2O)
is used for softening hard water.
Question 4:
What will happen if a solution of
sodium hydrocarbonate is heated? Give the equation of the reaction involved.
Answer
When a solution of sodium
hydrocarbonate (sodium hydrogencarbonate) is heated, sodium carbonate and water
are formed with the evolution of carbon dioxide gas.

Question 5:
Write an equation to show the reaction between Plaster of
Paris and water.
Answer
The chemical equation for the reaction of Plaster of Paris and water can
be represented as

Exercise solution Question 1:
A solution turns red litmus blue, its pH is likely to
be
(a) 1 (b) 4 (c) 5 (d) 10
Answer
(d) Bases turn red litmus blue and acids turn
blue litmus red. Basic solution has a pH value more than 7. Since the solution
turns red litmus blue, its pH is likely to be 10.
Question 2:
A solution reacts with crushed
egg-shells to give a gas that turns lime-water milky. The solution contains
(a) NaCl (b)
HCl (c) LiCl (d) KCl
Answer
(b) The
solution contains HCl.
Question 3:
10 mL of a solution of NaOH is
found to be completely neutralised by 8 mL of a given solution of HCl. If we
take 20 mL of the same solution of NaOH, the amount of HCl solution (the same
solution as before) required to neutralise it will be
(a) 4 mL (b) 8mL (c) 12 mL (d) 16 mL
Answer
(d) 16 mL of HCl
solution will be required.
Question 4:
Which one of the following types of medicines is used for
treating indigestion?
(a) Antibiotic
(b) Analgesic
(c) Antacid
(d) Antiseptic
Answer
(c) Antacid is used
for treating indigestion.
Question 5:
Write word
equations and then balanced equations for the reaction taking place when −
(a) dilute
sulphuric acid reacts with zinc granules.
(b) dilute
hydrochloric acid reacts with magnesium ribbon.
(c) dilute
sulphuric acid reacts with aluminium powder.
(d) dilute
hydrochloric acid reacts with iron filings.
Answer

Question 6:
Compounds such as alcohols and
glucose also contain hydrogen but are not categorized as acids. Describe an
activity to prove it.
Answer
Two nails are fitted on a cork and
are kept it in a 100 mL beaker. The nails are then connected to the two
terminals of a 6-volt battery through a bulb and a switch. Some dilute HCl is
poured in the beaker and the current is switched on. The same experiment is
then performed with glucose solution and alcohol solution.
Observations:
It will be observed that the bulb glows in the HCl solution and does not
glow in the glucose solution.

Result:
HCl dissociates into H+
and Cl− ions. These ions conduct electricity in the solution
resulting in the glowing of the bulb. On the other hand, the glucose solution
does not dissociate into ions. Therefore, it does not conduct electricity.
Conclusion:
From this activity, it can be
concluded that all acids contain hydrogen but not all compounds containing
hydrogen are acids.
That is why, though alcohols and
glucose contain hydrogen, they are not categorised as acids.
Question 7:
Why does distilled water not conduct electricity, whereas
rain water does?
Answer
Distilled water is a pure form of
water and is devoid of any ionic species. Therefore, it does not conduct
electricity. Rain water, being an impure form of water, contains many ionic
species such as acids and therefore it conducts electricity.
Question 8:
Why do acids not show acidic behaviour in the absence of
water?
Answer
Acids do not show acidic behaviour
in the absence of water because the dissociation of hydrogen ions from an acid
occurs in the presence of water only. It is the hydrogen ions that are
responsible for the acidic behaviour.
Question 9:
Five solutions A, B, C, D and E
when tested with universal indicator showed pH as 4, 1, 11, 7 and 9,
respectively. Which solution is (a)
neutral?
(b) strongly
alkaline?
(c) strongly
acidic?
(d) weakly
acidic?
(e) weakly
alkaline?
Arrange the pH in increasing order of hydrogen-ion concentration.
Answer
(a) Neutral →
Solution D with pH 7
(b) Strongly
alkaline → Solution C with pH 11
(c) Strongly
acidic → Solution B with pH 1
(d) Weakly
acidic → Solution A with pH 4
(e) Weakly
alkaline → Solution E with pH 9
The pH can be arranged in the
increasing order of the concentration of hydrogen ions as: 11 < 9 < 7
< 4 < 1
Question 10:
Equal lengths of magnesium ribbons
are taken in test tubes A and B. Hydrochloric acid (HCl) is added to test tube
A, while acetic acid (CH3COOH) is added to test tube B. In which
test tube will the fizzing occur more vigorously and why?
Answer
The fizzing will occur strongly in
test tube A, in which hydrochloric acid (HCl) is added. This is because HCl is
a stronger acid than CH3COOH and therefore produces hydrogen gas at
a faster speed due to which fizzing occurs.
Question 11:
Fresh milk has a pH of 6. How do you think the pH will
change as it turns into curd?
Explain your answer.
Answer
The pH of milk is 6. As it changes to curd, the pH will reduce because
curd is acidic in nature. The acids present in it decrease the pH.
Question 12:
A milkman adds a very small amount of baking soda to fresh
milk.
(a) Why does he
shift the pH of the fresh milk from 6 to slightly alkaline?
(b) Why does
this milk take a long time to set as curd?
Answer
(a)
The milkman shifts the pH of the fresh milk from 6 to
slightly alkaline because in alkaline condition, milk does not set as curd
easily.
(b)
Since this milk is slightly basic than usual milk,
acids produced to set the curd are neutralized by the base. Therefore, it takes
a longer time for the curd to set.
Question 13:
Plaster of Paris should be stored in a moisture-proof
container. Explain why?
Answer
Plaster of Paris (POP) should be
stored in a moisture-proof container because Plaster of Paris, a powdery mass,
absorbs water (moisture) to form a hard solid known as gypsum.

Question 14:
What is a neutralization reaction? Give two examples.
Answer
A reaction in which an acid and
base react with each other to give a salt and water is termed as neutralization
reaction. In this reaction, energy is evolved in the form of heat.
For example:
(i)

(ii) During indigestion (caused due to the production of
excess of hydrochloric acid in the
stomach), we administer an antacid (generally milk of
magnesia,
which is basic in nature). The
antacid neutralizes the excess of acids and thus gives relief from indigestion.


Question 15:
Give two important uses of washing soda and baking soda.
Answer
Two important used of washing soda and baking soda are as
follows:
(1) Washing soda:
(a) It is used
in glass, soap, and paper industries.
(b) It is used
to remove permanent hardness of water.
(2) Baking soda:
(a) It is used
as baking powder. Baking powder is a mixture of baking soda and a mild acid
known as tartaric acid. When it is heated or mixed in water, it releases CO2
that makes bread or cake fluffy.
(b) It is used
in soda-acid fire extinguishers.Question 1:
You have been provided with three
test tubes. One of them contains distilled water and the other two contain an
acidic solution and a basic solution, respectively. If you are given only red
litmus paper, how will you identify the contents of each test tube?
Answer
If the colour of red litmus paper
gets changed to blue, then it is a base and if there is no colour change, then
it is either acidic or neutral. Thus, basic solution can be easily
identified.
Let us mark the three test tubes as
A, B, and C. A drop of the
solution in A is put on the red
litmus paper. Same is repeated with solution B and C. If either of
them changes colour to blue, then it is basic. Therefore, out of three, one is
eliminated. Out of the remaining two, any one can be acidic or neutral. Now a
drop of basic solution is mixed with a drop of each of the remaining two
solutions separately and then the nature of the drops of the mixtures is
checked. If the colour of red litmus turns blue, then the second solution is
neutral and if there is no change in colour, then the second solution is
acidic. This is because acidic and basic solutions neutralize each other.
Hence, we can distinguish between the three types of solutions.
Why should curd and sour substances not be kept in brass and
copper vessels?
Answer
Curd and other sour substances contain acids. Therefore,
when they are
kept in brass and copper vessels,
the metal reacts with the acid to liberate hydrogen gas and harmful products,
thereby spoiling the food.
Question 2:
Which gas is usually liberated when
an acid reacts with a metal? Illustrate with an example. How will you test for
the presence of this gas?
Answer
Hydrogen gas is usually liberated when an acid reacts with a
metal.

Take few pieces of zinc granules
and add 5 ml of dilute H2SO4. Shake it and pass the gas
produced into a soap solution. The bubbles of the soap solution are formed.
These soap bubbles contain hydrogen gas.

We can test the evolved hydrogen
gas by its burning with a pop sound when a candle is brought near the soap
bubbles.
Question 3:
Metal compound A reacts with dilute
hydrochloric acid to produce effervescence. The gas evolved extinguishes a
burning candle. Write a balanced chemical equation for the reaction if one of
the compounds formed is calcium chloride.
Answer

Why do HCl, HNO3, etc.,
show acidic characters in aqueous solutions while solutions of compounds like
alcohol and glucose do not show acidic character?
Answer
The dissociation of HCl or HNO3
to form hydrogen ions always occurs in the presence of water. Hydrogen ions (H+)
combine with H2O to form hydronium ions (H3O+).
The reaction is as follows:

Although aqueous solutions of
glucose and alcohol contain hydrogen, these cannot dissociate in water to form
hydrogen ions. Hence, they do not show acidic character.
Question 2:
Why does an aqueous solution of an acid conduct electricity?
Answer
Acids dissociate in aqueous
solutions to form ions. These ions are responsible for conduction of
electricity.
Question 3:
Why does dry HCl gas not change the colour of the dry litmus
paper?
Answer
Colour of the litmus paper is
changed by the hydrogen ions. Dry HCl gas does not contain H+ ions.
It is only in the aqueous solution that an acid dissociates to give ions. Since
in this case, neither HCl is in the aqueous form nor the litmus paper is wet, therefore,
the colour of the litmus paper does not change.
Question 4:
While diluting an acid, why is it
recommended that the acid should be added to water and not water to the acid?
Answer
Since the process of dissolving an
acid in water is exothermic, it is always recommended that acid should be added
to water. If it is done the other way, then it is possible that because of the
large amount of heat generated, the mixture splashes out and causes burns.
Question 5:
How is the concentration of hydronium
ions (H3O+) affected when a solution of an acid is
diluted?
Answer
When an acid is diluted, the
concentration of hydronium ions (H3O+) per unit volume
decreases. This means that the strength of the acid decreases.
Question 6:
How is the concentration of
hydroxide ions (OH−) affected when excess base is dissolved in a
solution of sodium hydroxide?
Answer
The concentration of hydroxide ions
(OH−) would increase when excess base is dissolved in a solution of
sodium hydroxide.
You have two solutions, A and B.
The pH of solution A is 6 and pH of solution B is 8. Which solution has more
hydrogen ion concentration? Which of this is acidic and which one is basic?
Answer
A pH value of less than 7 indicates
an acidic solution, while greater than 7 indicates a basic solution. Therefore,
the solution with pH = 6 is acidic and has more hydrogen ion concentration than
the solution of pH = 8 which is basic.
Question 2:
What effect does the concentration of
ions have on the nature of the
solution?

Answer
Concentration of
can have a varied effect on the
nature of the solution. With an increase in H+ ion concentration,
the solution becomes more acidic, while a decrease of H+ ion causes
an increase in the basicity of the solution.

Question 3:

Answer
Yes, basic solution also has ions.
However, their concentration is less as compared to the concentration of OH−
ions that makes the solution basic.
Question 4:
Under what soil condition do you
think a farmer would treat the soil of his fields with quick lime (calcium
oxide) or slaked lime (calcium hydroxide) or chalk (calcium carbonate)?
Answer
If the soil is acidic and improper
for cultivation, then to increase the basicity of soil, the farmer would treat
the soil with quick lime or slaked lime or chalk.
Question 1:
What is the common name of the compound CaOCl2?
Answer
The common name of the compound CaOCl2 is
bleaching powder.
Question 2:
Name the substance which on treatment with chlorine yields
bleaching powder?
Answer
Calcium hydroxide [Ca (OH)2], on treatment with
chlorine, yields bleaching powder.
Question 3:
Name the sodium compound which is used for softening hard water.
Answer
Washing soda (Na2CO3.10H2O)
is used for softening hard water.
Question 4:
What will happen if a solution of
sodium hydrocarbonate is heated? Give the equation of the reaction involved.
Answer
When a solution of sodium
hydrocarbonate (sodium hydrogencarbonate) is heated, sodium carbonate and water
are formed with the evolution of carbon dioxide gas.

Question 5:
Write an equation to show the reaction between Plaster of
Paris and water.
Answer
The chemical equation for the reaction of Plaster of Paris and water can
be represented as

Exercise solution Question 1:
A solution turns red litmus blue, its pH is likely to
be
(a) 1 (b) 4 (c) 5 (d) 10
Answer
(d) Bases turn red litmus blue and acids turn
blue litmus red. Basic solution has a pH value more than 7. Since the solution
turns red litmus blue, its pH is likely to be 10.
Question 2:
A solution reacts with crushed
egg-shells to give a gas that turns lime-water milky. The solution contains
(a) NaCl (b)
HCl (c) LiCl (d) KCl
Answer
(b) The
solution contains HCl.
Question 3:
10 mL of a solution of NaOH is
found to be completely neutralised by 8 mL of a given solution of HCl. If we
take 20 mL of the same solution of NaOH, the amount of HCl solution (the same
solution as before) required to neutralise it will be
(a) 4 mL (b) 8mL (c) 12 mL (d) 16 mL
Answer
(d) 16 mL of HCl
solution will be required.
Question 4:
Which one of the following types of medicines is used for
treating indigestion?
(a) Antibiotic
(b) Analgesic
(c) Antacid
(d) Antiseptic
Answer
(c) Antacid is used
for treating indigestion.
Question 5:
Write word
equations and then balanced equations for the reaction taking place when −
(a) dilute
sulphuric acid reacts with zinc granules.
(b) dilute
hydrochloric acid reacts with magnesium ribbon.
(c) dilute
sulphuric acid reacts with aluminium powder.
(d) dilute
hydrochloric acid reacts with iron filings.
Answer

Question 6:
Compounds such as alcohols and
glucose also contain hydrogen but are not categorized as acids. Describe an
activity to prove it.
Answer
Two nails are fitted on a cork and
are kept it in a 100 mL beaker. The nails are then connected to the two
terminals of a 6-volt battery through a bulb and a switch. Some dilute HCl is
poured in the beaker and the current is switched on. The same experiment is
then performed with glucose solution and alcohol solution.
Observations:
It will be observed that the bulb glows in the HCl solution and does not
glow in the glucose solution.

Result:
HCl dissociates into H+
and Cl− ions. These ions conduct electricity in the solution
resulting in the glowing of the bulb. On the other hand, the glucose solution
does not dissociate into ions. Therefore, it does not conduct electricity.
Conclusion:
From this activity, it can be
concluded that all acids contain hydrogen but not all compounds containing
hydrogen are acids.
That is why, though alcohols and
glucose contain hydrogen, they are not categorised as acids.
Question 7:
Why does distilled water not conduct electricity, whereas
rain water does?
Answer
Distilled water is a pure form of
water and is devoid of any ionic species. Therefore, it does not conduct
electricity. Rain water, being an impure form of water, contains many ionic
species such as acids and therefore it conducts electricity.
Question 8:
Why do acids not show acidic behaviour in the absence of
water?
Answer
Acids do not show acidic behaviour
in the absence of water because the dissociation of hydrogen ions from an acid
occurs in the presence of water only. It is the hydrogen ions that are
responsible for the acidic behaviour.
Question 9:
Five solutions A, B, C, D and E
when tested with universal indicator showed pH as 4, 1, 11, 7 and 9,
respectively. Which solution is (a)
neutral?
(b) strongly
alkaline?
(c) strongly
acidic?
(d) weakly
acidic?
(e) weakly
alkaline?
Arrange the pH in increasing order of hydrogen-ion concentration.
Answer
(a) Neutral →
Solution D with pH 7
(b) Strongly
alkaline → Solution C with pH 11
(c) Strongly
acidic → Solution B with pH 1
(d) Weakly
acidic → Solution A with pH 4
(e) Weakly
alkaline → Solution E with pH 9
The pH can be arranged in the
increasing order of the concentration of hydrogen ions as: 11 < 9 < 7
< 4 < 1
Question 10:
Equal lengths of magnesium ribbons
are taken in test tubes A and B. Hydrochloric acid (HCl) is added to test tube
A, while acetic acid (CH3COOH) is added to test tube B. In which
test tube will the fizzing occur more vigorously and why?
Answer
The fizzing will occur strongly in
test tube A, in which hydrochloric acid (HCl) is added. This is because HCl is
a stronger acid than CH3COOH and therefore produces hydrogen gas at
a faster speed due to which fizzing occurs.
Question 11:
Fresh milk has a pH of 6. How do you think the pH will
change as it turns into curd?
Explain your answer.
Answer
The pH of milk is 6. As it changes to curd, the pH will reduce because
curd is acidic in nature. The acids present in it decrease the pH.
Question 12:
A milkman adds a very small amount of baking soda to fresh
milk.
(a) Why does he
shift the pH of the fresh milk from 6 to slightly alkaline?
(b) Why does
this milk take a long time to set as curd?
Answer
(a)
The milkman shifts the pH of the fresh milk from 6 to
slightly alkaline because in alkaline condition, milk does not set as curd
easily.
(b)
Since this milk is slightly basic than usual milk,
acids produced to set the curd are neutralized by the base. Therefore, it takes
a longer time for the curd to set.
Question 13:
Plaster of Paris should be stored in a moisture-proof
container. Explain why?
Answer
Plaster of Paris (POP) should be
stored in a moisture-proof container because Plaster of Paris, a powdery mass,
absorbs water (moisture) to form a hard solid known as gypsum.

Question 14:
What is a neutralization reaction? Give two examples.
Answer
A reaction in which an acid and
base react with each other to give a salt and water is termed as neutralization
reaction. In this reaction, energy is evolved in the form of heat.
For example:
(i)

(ii) During indigestion (caused due to the production of
excess of hydrochloric acid in the
stomach), we administer an antacid (generally milk of
magnesia,
which is basic in nature). The
antacid neutralizes the excess of acids and thus gives relief from indigestion.


Question 15:
Give two important uses of washing soda and baking soda.
Answer
Two important used of washing soda and baking soda are as
follows:
(1) Washing soda:
(a) It is used
in glass, soap, and paper industries.
(b) It is used
to remove permanent hardness of water.
(2) Baking soda:
(a) It is used
as baking powder. Baking powder is a mixture of baking soda and a mild acid
known as tartaric acid. When it is heated or mixed in water, it releases CO2
that makes bread or cake fluffy.
(b) It is used
in soda-acid fire extinguishers.
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